Invincible Iron Man #9 Issue: Invincible Iron Man (Vol 2) #9 Year: 2016 Significance: First Full Appearance of Riri Williams. The debut of her Prototype Armor. Buy on Ebay! View Recent Ebay! sold prices Previous Next Related The Terrific, The #1 Key Alerts, Modern Age Web of Spiderman #67 Golden Age, Noteworthy Issues Spectacular Spider-man #64 Black Keys, Bronze Age