Luke Cage Hero for Hire #5 Issue: Luke Cage Hero for Hire #5 Year: 1972 Significance: First Appearance of Black Mariah. Black Mariah is considered the First Black woman to ever be a supervillain in Marvel comics. Buy on Ebay! View Recent Ebay! sold prices Previous Next Related Spectacular Spider-man #64 Black Keys, Bronze Age Justice League Annual #2 Bronze Age, Noteworthy Issues Marvel Age Annual #4 Bronze Age, Noteworthy Issues