Luke Cage Hero for Hire #5 Issue: Luke Cage Hero for Hire #5 Year: 1972 Significance: First Appearance of Black Mariah. Black Mariah is considered the First Black woman to ever be a supervillain in Marvel comics. Buy on Ebay! View Recent Ebay! sold prices Previous Next Related Star Wars #6 Black Keys, Modern Age Avengers #278 Bronze Age, Noteworthy Issues, Undervalued Flash Rebirth #8 2016 Black Keys, Modern Age