Spidey Super Stories #11 Issue: Spidey Super Stories #11 Year: 1975 Significance: First Appearance of Spiderwoman in mainstream comics. This character was black, her name was Valerie the Librarian, and predates Jessica Jones as Spider-woman. Buy on Ebay! View Recent Ebay! sold prices Previous Next Related Brave and The Bold #24 2009 Noteworthy Issues, Undervalued Star Wars #6 Black Keys, Modern Age Avengers #278 Bronze Age, Noteworthy Issues, Undervalued